The solid C60 crystallizes in the fcc structure. In this respect, the fullerene molecules behave more or less like perfect spheres. In fact, at room temperature the buckyballs are not at rest: they rotate continuously and randomly. The fcc structure is well known from metallurgy: this is the most densely packed structure. However, there is a major structural difference between ordinary metals and the solid fullerene: with the C60 as a building block, there is plenty of empty space between the balls, even if the packing is as close as possible.
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